JOPSS - Search Results

Search Results: Records 1-5 displayed on this page of 5

Presentation/Publication Type

Initialising ...

Refine

Journal/Book Title

Initialising ...

Meeting title

Initialising ...

First Author

Initialising ...

Keyword

Initialising ...

Language

Initialising ...

Publication Year

Initialising ...

Held year of conference

Initialising ...

Journal Articles

Experimental determination of the photooxidation of aqueous I $^{-}$ as a source of atmospheric I $_{2}$

Watanabe, Kosuke*; Matsuda, Shohei; Cuevas, C. A.*; Saiz-Lopez, A.*; Yabushita, Akihiro*; Nakano, Yukio*

ACS Earth and Space Chemistry (Internet), 3(4), p.669 - 679, 2019/04

https://doi.org/10.1021/acsearthspacechem.9b00007

Times Cited Count：8 Percentile：43.59(Chemistry, Multidisciplinary)

The photooxidation of aqueous iodide ions (I $^{-}$ $_{(aq)}$ ) at sea surface results in the emission of gaseous iodine molecules (I $_{2}$ $_{(g)}$ ) into the atmosphere. It plays a certain role in the transport of iodine from ocean to the atmosphere in the natural cycle of iodine. In this study, we determined the photooxidation parameters, the molar absorption coefficient ( $_{iodide}$ ()) and the photooxidative quantum yields ( $_{iodide}$ ()) of I $^{-}$ $_{(aq)}$ , in the range of 290-500 nm. Through the investigation of the influence of pH and dissolved oxygen (DO) on $_{iodide}$ (), the subsequent emission rates of I $_{2}$ $_{(g)}$ following the photooxidation of I $^{-}$ $_{(aq)}$ in deionized water solution (pH 5.6, DO 7.8 mg L $^{-1}$ ) and artificial seawater solution (pH 8.0, DO 7.0 mg L $^{-1}$ ) were estimated. A global chemistry-climate model employed herein to assess the I $_{2}$ $_{(g)}$ ocean emission on a global scale indicated that the photooxidation of I $^{-}$ $_{(aq)}$ by solar light can enhance the atmospheric iodine budget by up to 8% over some oceanic regions.